Please use this identifier to cite or link to this item: http://dspace.sctimst.ac.in/jspui/handle/123456789/10562
Title: Synthesis, polymerization, and copolymerization of aliphatic vinyl azide
Authors: James, NR
Jayakrishnan, A
Keywords: Polymer Science
Issue Date: 2003
Publisher: JOURNAL OF APPLIED POLYMER SCIENCE
Citation: 87 ,11;1852-1857
Abstract: The synthesis and characterization of a fully aliphatic polymeric azide by polymerization of its vinyl monomer 1,3-diazidoisopropyl methacrylate (DAIPM) is reported. DAIPM was prepared by azidation of epichlorohydrin followed by coupling with methacrylic acid. Homopolymer and copolymers with methyl methacrylate were prepared and characterized by IR, GPC, TGA, DTA, and elemental analyses. These polymers are freely soluble in organic solvents like dichloromethane, tetrahydrofuran, di-methyl formamide, acetone, and so forth and do not crosslink on storing. The polymers show decreased thermal stability with an increase in azide content and undergo exothermic decomposition on heating. (C) 2003 Wiley Periodicals, Inc. Inc.
URI: 10.1002/app.11507
http://dspace.sctimst.ac.in/jspui/handle/123456789/10562
Appears in Collections:Journal Articles

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.