Browsing by Author "Krishnan, V"
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Item Development and evaluation of two PVD-coated beta-titanium orthodontic archwires for fluoride-induced corrosion protection(ACTA BIOMATERIALIA, 2011) Krishnan, V; Krishnan, A; Remya, R; Ravikumar, KK; Nair, SA; Shibli, SMA; Varma, HK; Sukumaran, K; Kumar, KJThe present research was aimed at developing surface coatings on beta titanium orthodontic archwires capable of protection against fluoride-induced corrosion. Cathodic arc physical vapor deposition PVD (CA-PVD) and magnetron sputtering were utilized to deposit thin films of titanium aluminium nitride (TiAIN) and tungsten carbide/carbon (WC/C) coatings on beta titanium orthodontic archwires. Uncoated and coated specimens were immersed in a high fluoride ion concentration mouth rinse, following a specially designed cycle simulating daily use. All specimens thus obtained were subjected to critical evaluation of parameters such as electrochemical corrosion behaviour, surface analysis, mechanical testing, microstructure, element release, and toxicology. The results confirm previous research that p titanium archwires undergo a degradation process when in contact with fluoride mouth rinses. The study confirmed the superior nature of the TiAIN coating, evident as many fewer changes in properties after fluoride treatment when compared with the WC/C coating. Thus, coating with TiAIN is recommended in order to reduce the corrosive effects of fluorides on beta titanium orthodontic archwires. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.Item Development, characterization and comparison of two strontium doped nano hydroxyapatite molecules for enamel repair/regeneration(Dental Materials., 2016-06) Krishnan, V; Bhatia, A; Varma, HKObjectives. Enamel damage resulting or arising from/associated with orthodontic treatmentsuch as white spot lesions and surface deterioration after debonding brackets along withincipient carious lesions are considered problems not amenable for routine restorations dueto its invasive nature. The present study was aimed at synthesizing and characterizing nHApand 25 and 50 mol% strontium nHAp as a surface application modality for dental enamelremineralization/repair.Methods. 25 and 50 mol% Sr nHAp was synthesized and characterized in comparison withcustom made pure nHAp initially with the help of transmission and scanning electronmicroscopy as well as toxicological assessment. Further, comparative evaluation of thesenovel synthesized strontium substituted particles was assessed for its efficacy in repairingdamaged enamel with the help of atomic force microscopy, scanning electron microscopyand micro indentation testing.Results. There is increase in crystallinity and reduced particle size favoring dissolution andre-precipitation through small incipient carious lesions and soft white spot areas with 25%Sr-nHAp. Sr doped specimens showed more cell viability in comparison with pure nHAPmake it less cytotoxic and hence a biologically friendly material which can be safely appliedin patient’s mouth. AFM images obtained from 25% and 50% Sr nHAp treated specimensclearly indicated increased roughness in surface topography and performed well with microindentation test.Significance. The novel synthesized Sr doped nHAp forms an improved treatment modality totackle the long standing quest for solving the problem of enamel loss with incipient cariouslesions and WSL from orthodontic procedures.